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Him being offended enough for it to be a problem by you asking a clear, good faith question isn’t “over nothing”.

So should I just ask him directly that why is he asking me to hangout with him one on one?

Literally yes.

Will he not be offended?

If he’s offended by open, clear communication, that’s a good sign you shouldn’t continue trying to be friends anyways.

FOSS alternatives are nice.

That would destroy the majority of Lemmy though